|
KMID : 0895420090190040403
|
|
Journal of Korean Society of Occupational and Enviromental Hygiene
2009 Volume.19 No. 4 p.403 ~ p.411
|
|
|
Study on desorption efficiency of naphthalene by adsorbing media and desorbing solvent
|
|
Choi Jin-Hee
Lee Kwon-Seob
Shin Hyeon-Hwa
Yang Jeong-Sun
|
|
|
Abstract
|
|
|
|
This study was performed to propose appropriate conditions suited to the analysis of naphthalene by comparing desorption efficiencies under various conditions. 1. As to influence by adsorbing media and desorbing solvent on desorption efficiency of naphthalene, when adsorbed by CCT, o-xylene gave the highest desorption efficiency of 73.96±0.53% while the lowest of 1.14±0.03% desorbed by ether. Both XAD-2 and Chromosorb 106 showed around 90% of desorption efficiencies for each solvent, especially desorption efficiencies more than 95% were achieved when adsorbed by Chromosorb 106 and desorbed by CS2 or o-xylene. 2. Desorption efficiencies descended over the storage period in any condition(p<0.05). For all three adsorbing media, while desorption efficiencies showed no significant difference(p>0.05) between room temperature and refrigeration a day of loading, samples kept in room temperature had higher desorption efficiencies than refrigerated ones in 7 and 14 days with significant difference(p<0.05).Also, desorption efficiencies dropped drastically in 7 days, from that point the decreasing tendency went mild. 3. When respective 1 TLV and 0.1 TLV of naphthalene were spiked on CCT and desorbed by CS2(46.45±0.59% vs. 30.15±0.81%), o-xylene(73.96±0.53% vs. 67.51±1.34%), and ether(1.14±0.03% vs. N.D.) desorption efficiencies increased as the amount of loading increased(p<0.05).On the other hand, naphthalene spiked on XAD-2 and Chromosorb 106 indicated no significant difference(p>0.05) in desorption efficiencies between 1 TLV and 0.1 TLV. In conclusion, in order for favorable desorption efficiencies of naphthalene it is important to select appropriate adsorbing media and desorbing solvent accordingly. The result revealed that adsorbing media of XAD-2 and Chromosorb 106 outperformed CCT and desorbing solvents of CS2 and o-xylene achieved over 90% of desorption efficiencies when adsorbed on XAD-2 and Chromosorb 106. Also, considering the tendency that desorption efficiencies of naphthalene decrease with time, the samples should be analyzed as soon as possible.
|
|
|
KEYWORD
|
|
|
Naphthalene, desorption efficiency, storage stability
|
|
|
FullTexts / Linksout information
|
|
|
|
|
|
Listed journal information
|
|
|
|